Biodiesel production made easy with waste-recycling catalyst

Source: University of Cardiff

Cardiff, Wales – Researchers from the Cardiff Catalysis Institute have devised a way of increasing the yield of biodiesel by using the waste left over from its production process. Using simple catalysis, the researchers have been able to recycle a non-desired by-product produced when biodiesel is formed from vegetable oil, and convert this into an ingredient to produce even more biodiesel. It is believed this new process will have significant environmental benefits by improving the yield of biodiesel in a sustainable way that doesn’t require the use of additional fossil fuels, and could potentially reduce the costs of the biodiesel production process.

At present, biodiesel is produced by combining fats and oils with methanol, which is usually derived from fossil fuels. A waste product from this process is crude glycerol, which is formed on a large scale and contains many impurities that make it costly to purify and re-use in other areas. In their study, the researchers developed a way of turning the crude glycerol back into methanol, which could then be used as a starting reactant to create more biodiesel.

To achieve this, the researchers reacted glycerol with water, to provide the element hydrogen, and a magnesium oxide (MgO) catalyst. The reaction involved a simple one-step process and could be performed using mild conditions. Using the recycled methanol, the researchers estimate up to a 10 per cent increase in biodiesel production, which they claim would be very helpful to industry at this point in time.

To manufacture biodiesel more environmentally friendly

The work is currently in its early stages and in future studies the researchers will look to optimise the design of the catalyst and significantly increase its activity and selectivity. Lead author of the study Professor Graham Hutchings, Director of the Cardiff Catalysis Institute, underlined: “Biodiesel manufacture is a growing part of the EU fuel pool, with statutory amounts being required to be added to diesel that is derived from fossil fuels. We’ve provided unprecedented chemistry that highlights the potential to manufacture biodiesel in a much more environmentally friendly, and potentially cheaper, way, by converting an undesired by-product into a valuable chemical that can be reused in the process.”

Co-author of the study Professor Stuart Taylor, Deputy Director of the Cardiff Catalysis Institute, agued: “We set out to establish ways in which the waste product glycerol could be used to form other useful compounds, but we were surprised when we found that feeding glycerol and water over such a simple catalyst gave such valuable products and interesting chemistry. This research has the potential to transform the way in which waste is dealt with, and seriously improve the quality of life by reducing carbon emissions from fossil fuels and encourage efficient use of resources.”

Original source: Efficient green methanol synthesis from glycerol‘. Nature Chemistry. Muhammad H. Haider*†, Nicholas F. Dummer, David W. Knight, Robert L. Jenkins, Mark Howard, Jacob Moulijn, Stuart H. Taylor and Graham J. Hutchings*. 14 September 2015. DOI:10.1038/nchem.2345

Source: University of Cardiff